Phase transition enhanced thermoelectric figure-of-merit in copper chalcogenides
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چکیده
منابع مشابه
Influence of Compensating Defect Formation on the Doping Efficiency and Thermoelectric Properties of Cu2‐ySe1−xBrx
The superionic conductor Cu2−δSe has been shown to be a promising thermoelectric at higher temperatures because of very low lattice thermal conductivities, attributed to the liquid-like mobility of copper ions in the superionic phase. In this work, we present the potential of copper selenide to achieve a high figure of merit at room temperature, if the intrinsically high hole carrier concentrat...
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The (Bi0.25 Sb0.75)2Te3 compound is a p-type thermoelectric semiconductor for application in thermoelectric cooling systems. To fabricate this single crystal, required elements, Bi, Sb and Te with 5N purity melted in quartz capsule at 10-6 torr pressure and rapidly quenched to room temperature. The sample crystallized by zone melting method with the rate of 8 mm per an hour at 700 oC and for...
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PbSe is a surprisingly good thermoelectric material due, in part, to its low thermal conductivity that had been overestimated in earlier measurements. The thermoelectric figure of merit, zT, can exceed 1 at high temperatures in both p-type and n-type PbSe, similar to that found in PbTe. While the p-type lead chalcogenides (PbSe and PbTe) benefit from the high valley degeneracy (12 or more at hi...
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Tin selenide has attracted much research interest due to its unprecedentedly high thermoelectric figure of merit (ZT). For real applications, it is desirable to increase the ZT value in the lower-temperature range, as the peak ZT value currently exists near the melting point. It is shown in this paper that the structural phase transition plays an important role in boosting the ZT value of SnSe ...
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تاریخ انتشار 2013